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AP Chemistry Chapters 11, 12, 13

Definition Tables, Graphs, Pictures Equations Comparison Calculations
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What is the energy required to increase the surface area of a liquid by a unit amount?

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What is the energy required to increase the surface area of a liquid by a unit amount?


Surface Tension


What are the attractive forces between the positive end of one polar molecule and the negative end of another polar molecule

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What are the attractive forces between the positive end of one polar molecule and the negative end of another polar molecule


Dipole-Dipole Forces


What is superconductivity?

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What is superconductivity?


Frictionless flow of electrons through a substance.


 
The process by which solvent molecules surround and interact with solute ions or molecules is called...
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The process by which solvent molecules surround and interact with solute ions or molecules is called...

Solvation.


What is the degree of randomess or disorder in a system given by a thermodynamic quantity?

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What is the degree of randomess or disorder in a system given by a thermodynamic quantity?


Entropy


 

Is this a Polar or a Non-Polar Bond?

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Is this a Polar or a Non-Polar Bond?


It is very polar.


What kind of bonding is present here. 

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What kind of bonding is present here. 


Hydrogen bonding or London dispersion forces . 


What are these structures representing?

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What are these structures representing?


Polymers


Pentane        

 

Which one is more polar?

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Pentane        

 

Which one is more polar?


C5H11OH


What is this structure?

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What is this structure?


Vitamin A!


Write a chemical equation that represents the formation of polychloroprene from chloroprene.

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Write a chemical equation that represents the formation of polychloroprene from chloroprene.


CH2=CClCH=CH2 --> -[-CH2CCl=CHCH2-]-n


Write a chemical equation that represents the formation of polyacrylonitrile from acryonitrile1

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Write a chemical equation that represents the formation of polyacrylonitrile from acryonitrile1


CH2=CHC*N --> -[-CH2CH(C*N)-]-n


Write a chemical equation for formation of a polymer via a condensation reaction from the monomers succinic acid (HOOCCH2CH2COOH) and ethylenediamine (H2NCH2CH2NH2)

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Write a chemical equation for formation of a polymer via a condensation reaction from the monomers succinic acid (HOOCCH2CH2COOH) and ethylenediamine (H2NCH2CH2NH2)



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Which member of the following pairs has the stronger intermolecular dispersion force:

 

Br2 or O2

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Which member of the following pairs has the stronger intermolecular dispersion force:

 

Br2 or O2


Br2


Which member of the following pairs has the larger London dispersion forces:

 

H2O or H2S

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Which member of the following pairs has the larger London dispersion forces:

 

H2O or H2S


H2S


What is the difference between a monomer and a polymer?

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What is the difference between a monomer and a polymer?


A monomer is a single structure and has low moleculer weight, while a polymer consists of several monomers and appears like plastic such as shellac and varnish. A polymer has higher molecular weight.


List the three states of matter in order of increasing molecular disorder and increasing intermolecular attractions.

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List the three states of matter in order of increasing molecular disorder and increasing intermolecular attractions.


The solid state has the least amount of disorder, the liquid state is intermediate between the solid and gaseous state, the gas state is the most disordered. The intermolecular forces are the strongest in the solid, intermediate in the liquid phase, and weakest in the gas phase.


For each of the follwing pairs of semiconductors, which one will have the larger band gap: 

A) CdS or CdTe

B) GaN or InP

C) GaAs or InAs

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For each of the follwing pairs of semiconductors, which one will have the larger band gap: 

A) CdS or CdTe

B) GaN or InP

C) GaAs or InAs


A)CdS

B)GaN

C)GaAs


Calculate the mass percentage of Na2SO4 in a solution containing 10.6 g Na2SO4 in 483 g water.

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Calculate the mass percentage of Na2SO4 in a solution containing 10.6 g Na2SO4 in 483 g water.


2.15% Na2SO4 by mass


Calculate the molarity of each of the follwing solutions:

A)8.66 g benzene (C6H6) dissolved in 23.6 g carbon tetrachloride (CCl4)

B) 4.80 g NaCl dissolved in 0.350 L of water

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Calculate the molarity of each of the follwing solutions:

A)8.66 g benzene (C6H6) dissolved in 23.6 g carbon tetrachloride (CCl4)

B) 4.80 g NaCl dissolved in 0.350 L of water


A) 4.70 M C6H6

B)0.235 M NaCl


You are given 12.0 g of ice at -5.00 °C. How much energy is needed to melt the ice completely to water?

q = (mass) (Δt) (Cp)

 

q = (moles of water) (ΔHvap)

View Answer

You are given 12.0 g of ice at -5.00 °C. How much energy is needed to melt the ice completely to water?

q = (mass) (Δt) (Cp)

 

q = (moles of water) (ΔHvap)


q = (12.0 g) (5.0 °C) (2.06 J g¯1 °C¯1)

q = 123.6 J = 0.1236 kJ

             +

q = (12.0 g) (5.0 °C) (2.06 J g¯1 °C¯1)

q = 123.6 J = 0.1236 kJ

             =

         4.14 kJ


For many years drinking water has been cooled in hot climates by evaporating it from the surfaces of canvas bags or porous clay pots. How many grams of water can be cooled from 35 C to 20 C by the evaporation of 60 g of water? (The heat of vaporization of water in this temperature range is 2.4 kJ/g. The specific heat of water is 4.18 J/g-K.)

 

q = (mass) (Δt) (Cp)

q = (moles of water) (ΔHvap)

View Answer

For many years drinking water has been cooled in hot climates by evaporating it from the surfaces of canvas bags or porous clay pots. How many grams of water can be cooled from 35 C to 20 C by the evaporation of 60 g of water? (The heat of vaporization of water in this temperature range is 2.4 kJ/g. The specific heat of water is 4.18 J/g-K.)

 

q = (mass) (Δt) (Cp)

q = (moles of water) (ΔHvap)


2.3*10^3 g H2O


Ethanol (C2H5OH) melts at -144 C and boils at 78 C. Its density is 0.789 g/mL. The enthalpy of fusion of ethanol is 5.02 kJ/mol. The specific heats of solid and liquid ehtanol are 0.97 J/g-K and 2.3 J/g-K, respectively.

A)How much ethanol is required to to convert 25.0 g of ethanol at 25 C to the vapor phase at 78 C? 

B) How much heat is required to convert 5.00 L of ethanol at -140 C to the vapor phase at 78 C?

View Answer

Ethanol (C2H5OH) melts at -144 C and boils at 78 C. Its density is 0.789 g/mL. The enthalpy of fusion of ethanol is 5.02 kJ/mol. The specific heats of solid and liquid ehtanol are 0.97 J/g-K and 2.3 J/g-K, respectively.

A)How much ethanol is required to to convert 25.0 g of ethanol at 25 C to the vapor phase at 78 C? 

B) How much heat is required to convert 5.00 L of ethanol at -140 C to the vapor phase at 78 C?


A) 24.0 kJ

B) 5.57*10^3 kJ



View Answer





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